If you turn the motor over enough you will end up with the cams out and marks lined up. It's not a 1:1 ratio
Right. I thought about this some more, and came to the same revelation. Obviously the chain is longer than the circumference of the drive sprocket, so the master link isn't going to end up in the same place with each revolution. Further, Alfa engines with different stroke lengths (1300 - 1600 - 1750 & 2L) use upper timing chains of different length, but the same sprocket diameters. So each of those will have a different multiple of engine rotation to chain rotation.
I'm not so worried about the link coming off from the motor accelerating faster than the mass of the link. I'm worried about the motor stopping faster than the link which if it seized up the link could not fly off.
Actually, I'm not worried about either scenario. The force due to acceleration/deacceleration on the snap link is trivial compared to the force required to pop it off. The thing weighs practically nothing - it would take about a million G's (*) to get it to unsnap. There is no way that the entire rotational mass of the engine could accelerate quickly enough to dislodge the snap link - the chain would fracture first.
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* OK, in thinking about this some more, perhaps "a million G's" was a little on the high side. How much force would you think it takes to snap the thing in place, say 5 pounds? And what would you guess it weights, maybe 1/4 ounce? So 5 # X 16 oz/# / .25 oz = 320 G's. Not quite a million, but enough to make Chuck Yaeger black out!