Not mixture, but velocity.
Longer runners, up to a point, make for faster airflow which in turn can improve lower RPM performance.
Faster airflow gives a slightly bigger mixture charge to the cylinder without having to spool up the revs.
(volumetric efficiency, harmonic pulses, long hair math stuff)
Mixture will be controlled by the ECU via oxygen and other sensor input and/or pre~programmed mapping regardless of runner length or the presence of a single or multiple throttle bodies.
The very loose way about it is long runners improve low end, short runners improve high end. Finding a balance that gets your power curve where you want it and matched to the camshaftery is where actual math needs to be done if you want the most out of it.
AFA the L-jet and motronic EFI standard plenum runners, they are actually quite long already (as long or longer than any ITB's I've seen anyway) and quite efficient at what they are designed for. The single throttle body in those systems could be enlarged a bit, but in general it helps give better off idle and low end drivability over individual throttle bodies as those tend to be lacking a bit on thier ability to actually hold any kind of real vacuum levels in the bottom ranges.
If the vacuum levels are too low, then the mixture flow into the cylinders is inefficient and you end up with things like bog and flat spots until you either tune it out through whatever means (cams usually) or get the revs up into a range where the velocity improves.