Congrats on your purchase and welcome to the AlfaBB!
After perusing a number of Alfa published documents, I found only one document that references a prefix letter in the type 00548 1750 sequential engine number. The letter 'S' is referenced in Technical Service Bulletin (TSB) #04.73.2.2 dated 16 May 73 to indicate an engine thus stamped is equipped with an emcon (EMission CONtrol) system.
I could find no reference to a letter 'B' in a 1750s sequential serial number. This does not mean however that a B prefix does not exist, it simply means that I do not have any information on it.
The same holds true for 1750 engines being installed into Spider 1600s at the factory; it may have happened but I've no documentation to verify it.
If the letter B in your engine number is indeed the number 8, this would make engine 82319 a late Series 1 1750 (Series 2 engines [for the 1970 model year], according to Alfa Information Sheet (IS) #03.70.2.1 dated 21 May 70 start with engine #90001). If this is the case, then an engine swap has taken place.