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The first production V6 cars that used the trigger wheel were the 164, the Alfa SZ and the 75 3.0V6 LE (1992). All were 3.0V6 engines.
The first Alfa 155V6's produced in 1993 had the first 2.5V6 (12-valve) that used the trigger wheel, and was replaced with the Alfa 156 2.5 that had the 24-valve 2.5V6. The latter employed COP (coil-on-plug) for ignition.
As for replacing the v-belt drive with the serpentine drive, you could simply take a 164 3.0V6 front pulley and have a crank balance shop re-counterweight it to your 2.5V6's flywheel.
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