Jet Hott and similar coatings are mostly cosmetic and do very little as far as heat soak from the headers.
A true thick ceramic coating inside and out is the only cure. Unfortunately the word "ceramic" get abused and used by marketing. Look at Swain Technologies and at their coatings technology. They are truly superior as well as a few other true ceramic providers.
I have used their header coating on Olds 455 headers in a GMC motorhome and they reduced engine compartment temps by about 40 to 50 degrees. I had engine compartment temps close to 190 degrees on hot days. After the Swain coating the temps went down to 140-150 on 80 degree days. I had a 4 temp gauges in the engine compartment and could monitor it directly.
Its not pretty, but it works. Guess you have to decide between show and go.
Take a look:
Racing Coatings - Automotive Coatings from Swain Tech including engine piston coatings, ceramic coating services engine, automotive ceramic coating, ceramic header coating, dry film lubricant, race engine coatings, exhaust header coating
I am not affiliated with Swain Technology in any way other than being a satisfied customer.
I plan on using their coatings on my 24 Valve engine build. Pistons skirts and tops, bearings, valves and heads as well as the headers. They are not inexpensive, but well worth the cost when you figure in the cost of hard to find and expensive parts.
Marcus